What is silica
gel?
Silica gel, namely the gel of silicon dioxide, is a
highly active adsorbing material with micro-pore structure that is
usually formed through the reaction between sodium silicate and
sulfuric acid, polymerization and gelatinized, depurated and drying.
Silica gel is a non-crystalline state substance that is mainly
composed of silicon dioxide and has a certain amount of constitution
water. Due to its chemical and physical structural characteristics,
silica gel has many superior qualities that other similar materials
can never replace, such as the adsorbability, selective absorption,
and thermal stability, chemical stability, abrasion proof, dynamic
resistance and so on.
Silica gel was generated in 1881 and was only used as a
military material till the First World War with small-scale
preparation. At the
beginning of 20th century, its semi-industrialized production
started. After the Second World War, as the rapid development of the
modernized industries, all the industrialized countries gained
impressive advances in the research and development of silica gel
products. As an absorbent, dispersant, reinforcing agent, catalyzer
and catalyzer carrier, silica gel has been used in many fields like
the chemistry, rubber, plastic, petrol-chemistry, heavy industry,
medicine and foodstuffs.
The production of silica gel started in China since 1955,
after half century, from the single lump silica gel product into
dozens kinds of products for various uses, such as spherical-shaped
silica gel, micro-spherical shaped silica gel, activated silica gel,
color-changing silica gel, big-pore silica gel, high-efficiency
desiccant and so on. At present, the total domestic silica gel
production capacity has reached about 100,000 tons annually, 70% of
which are sold to the overseas market.
Silica
gel’s main characteristics ---- Adsorbability
Silica gel’s absorptive action includes two
processes: the absorption and the coacervation. The
absorption is connected with the surface and the coacervation with
the diameter of the pore. They both depend on the relative pressure
of the adsorbate. Take the water vapor as an
example.
Silica gel’s adsorptive capacity for the water
vapor will reinforce along with the air relative humidity enhances,
but the adsorptive capacity of different pore-sized silica gels have
different changing rules. Under the same relative humidity, their
absorptive capacity performances are variable. This kind of regular changes
are usually described with the curve of adsorption isotherm, as
shown below:
We can see that fine-pore silica gel has a
higher adsorptive capacity under the low relative humidity; whereas
the wide-pore silica gel has a relatively high adsorptive capacity
under the high relative humidity. So we may choose the appropriate
silica gel products according to different environments and
conditions to gain the best effect.